6. If non-zero vectors $\mathbf { a } , \mathbf { b }$ satisfy $| \mathbf { a } | = \frac { 2 \sqrt { 2 } } { 3 } | \mathbf { b } |$ and $(\mathbf{a}-\mathbf{b})\perp(3\mathbf{a}+2\mathbf{b})$, then the angle between $\mathbf { a }$ and $\mathbf { b }$ is\\
A. $\frac { \pi } { 4 }$\\
B. $\frac { \pi } { 2 }$\\
C. $\frac { 3 \pi } { 4 }$\\
D. $\pi$