jee-advanced 2012 Q24

jee-advanced · India · paper2 Not Maths
24. The shape of $\mathrm { XeO } _ { 2 } \mathrm {~F} _ { 2 }$ molecule is
(A) trigonal bipyramidal
(B) square planar
(C) tetrahedral
(D) see-saw
ANSWER : D
  1. For a dilute solution containing 2.5 g of a non-volatile non-electrolyte solute in 100 g of water, the elevation in boiling point at 1 atm pressure is $2 ^ { \circ } \mathrm { C }$. Assuming concentration of solute is much lower than the concentration of solvent, the vapour pressure ( mm of Hg ) of the solution is (take $K _ { \mathrm { b } } = 0.76 \mathrm {~K} \mathrm {~kg} \mathrm {~mol} ^ { - 1 }$ )
    (A) 724
    (B) 740
    (C) 736
    (D) 718

ANSWER:A
  1. The compound that undergoes decarboxylation most readily under mild condition is

(A) [Figure]
(B) [Figure]
(C) [Figure]
(D) [Figure]
ANSWER : B
In allene $\left( \mathrm { C } _ { 3 } \mathrm { H } _ { 4 } \right)$, the type(s) of hybridization of the carbon atoms is (are)
24. The shape of $\mathrm { XeO } _ { 2 } \mathrm {~F} _ { 2 }$ molecule is\\
(A) trigonal bipyramidal\\
(B) square planar\\
(C) tetrahedral\\
(D) see-saw

\section*{ANSWER : D}
\begin{enumerate}
  \setcounter{enumi}{24}
  \item For a dilute solution containing 2.5 g of a non-volatile non-electrolyte solute in 100 g of water, the elevation in boiling point at 1 atm pressure is $2 ^ { \circ } \mathrm { C }$. Assuming concentration of solute is much lower than the concentration of solvent, the vapour pressure ( mm of Hg ) of the solution is (take $K _ { \mathrm { b } } = 0.76 \mathrm {~K} \mathrm {~kg} \mathrm {~mol} ^ { - 1 }$ )\\
(A) 724\\
(B) 740\\
(C) 736\\
(D) 718
\end{enumerate}

\section*{ANSWER:A}
\begin{enumerate}
  \setcounter{enumi}{25}
  \item The compound that undergoes decarboxylation most readily under mild condition is
\end{enumerate}

(A)\\
\includegraphics[alt={}]{smile-06b81ac4773af826fe47a69c684c12f617530ede}

(B)\\
\includegraphics[alt={}]{smile-cfdc774045655ebcb9c844c007a6f80a59316b40}

(C)\\
\includegraphics[alt={}]{smile-10ff3e665ee1672398f01712708520194ebfee07}

(D)\\
\includegraphics[alt={}]{smile-a4d3ea3a611b0a08b028134d389310e65ed1c567}

ANSWER : B\\